This may help you,

go to whitepapers --> Documentation

http://technet.microsoft.com/en-us/appvirtualization/bb508934.aspx

You can also check YouTube. There are alot of helpful videos to get you started.

Whitepapers documents from Microsoft is the best place to start with. Once you get to know the basic concept, you can go through the available virtual lab. Here is the link:

http://technet.microsoft.com/en-us/virtuallabs/ee862412

We provide training on Adminstudio and AppV, contact me on Arjun@apprepack.in for further details.